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Champions League: Arsenal vs. Olympiacos Picks, Odds, and Preview (Oct 1)

  • Alex Dudley
  • Sep 30, 2025 at 7:22 AM EDT

Pick rationale

Analysis & key factors

Arsenal will be aiming to maintain their 100% record at the start of the Champions League when they take on Olympiacos at the Emirates on Wednesday. The Greek side endured a disappointing start to the competition, and will be huge outsiders when making Arsenal vs. Olympiacos picks this week.


Event Overview

  • When: Wednesday, October 1, 2025. 3:00 PM ET
  • Where: Emirates Stadium, London, England
  • How to Watch: CBS

Arsenal vs. Olympiacos Odds

Match ResultOdds
Arsenal-513
Draw+545
Olympiacos+2000

Head-to-Head Record

Arsenal and Olympiacos will clash for the 13th time across all competitions this week. There is yet to be a draw when the teams have collided, with both winning on six occasions. In fact, Arsenal have won twice and lost twice in four matches against the Greeks under Mikel Arteta.

ALSO SEE: Alfred Dunhill Links Championship Picks, Odds, and Preview (Oct 2-5)


Match Preview

Arsenal made a winning start to the Champions League this season on matchday one after dominating Athletic Club and claiming a 2-0 success on the road. Gabriel Martinelli broke the deadlock late, before a second was added by Leandro Trossard.

It was a forgettable start to the 2025-26 Champions League for Olympiacos, as they struggled to breakdown competition newcomers Pafos. A 0-0 draw was played out, marking the second goalless draw involving the Greeks in 54 matches.

Interestingly, Olympiacos have won two of their last three away matches in England. Their most recent success was achieved in the West Midlands against Aston Villa in May 2024.

However, Arsenal have a dominant record in the Champions League opening round, having won each of their last five. That is their best winning sequence in the competition since November 2005.


Arsenal vs. Olympiacos Picks

Arsenal have stuttered for goals already this season, but they produced a season-best display to overcome Newcastle in the Premier League on Sunday. The confidence gained from that success should ensure that they are very difficult to beat in the Champions League on Wednesday.

Free Pick:

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