Champions League: Barcelona vs. PSG Picks, Odds, and Preview (Oct 1)

Two of the biggest club teams in Europe will collide on matchday two in the Champions League on Wednesday, October 1. Both Barcelona and PSG kicked off their European campaigns with victories, but which side will maintain their winning sequence in Catalonia? Find out picks here.

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Event Overview

• When: Wednesday, October 1, 2025. 3:00 PM ET
• Where: Estadi Olimpic Lluis Companys, Barcelona, Spain
• How to Watch: CBS

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Barcelona vs. PSG Odds

Match Result	Odds
Barcelona	-115
Draw	+329
PSG	+275

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Head-to-Head Record

A 16^th European meeting between Barcelona and PSG is set for Wednesday. Barcelona holds the narrow advantage; having recorded six wins to PSG’s five. Four draws have also been played out when these sides have collided.

ALSO SEE: Alfred Dunhill Links Championship Picks, Odds, and Preview (Oct 2-5)

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Match Preview

Hansi Flick’s Barcelona were our pre-tournament picks to win the Champions League this season. The La Liga champions got off to the perfect start on matchday one after claiming a 2-1 success in England against Newcastle United. Marcus Rashford was the match-winner, netting both goals in the second half.

PSG made a dominant opening impression on matchday one, as they landed an excellent 4-0 success against Atalanta. The success means that the Parisians have now won eleven of their last 13 matches in the Champions League, and they have netted at least two goals in ten fixtures across that period.

Despite holding the head-to-head advantage, Barcelona have won just two of their last six against PSG. However, the La Liga champions still boast a dominant home record in the competition, winning nine of their last 12.

PSG’s attacking players have sparkled in the competition across the last two seasons. That is indicated by the fact that they have scored 12 and conceded just once across their last four matches in the Champions League.

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Barcelona vs. PSG Picks

A fascinating early season meeting between two of the biggest teams in Europe is set for Wednesday. At the prices, PSG could be an interesting betting angle, especially against a rival that have been leaky defensively in the Champions League across the last two seasons.

Free Pick:

• PSG (+275)